Which chemicals in smog obscure visibility?

I know that smog is generally a mixture of various chemicals, such as peroxyacetyl nitrate (PAN) and ozone. I also know that smog obscures visibility.

My question is two-fold:

1. What chemical in smog generally obscures visibility (discounting aerosols)?
2. Is there a relationship between the concentrations of the chemical and the optical depth/visibility of the smog?
• It's not only “chemicals”, but also particulate matter, which I believe dominates the causes of reduced visibility. I'm not sure about it, which is why I post a comment rather than an answer. – gerrit Jun 20 '17 at 11:05
• – f.thorpe Jun 20 '17 at 16:38

1. Basic concepts of visibility loss

The deterioration of visibility can be divided into four parts as follows:

absorption of gases + scattering of gases + absorption of aerosol + scattering of aerosol

quote from a Ph.D dissertation link here

scattering is a process where the incident radiation is reradiated into all directions after interacting with a scattering point.

In the visible zone (400 nm - 700 nm), the cloud free atmosphere is remarkably transparent, This means that the absorption of the radiation at visible band occurs primarily at the surface and not within the atmosphere itself.

We can derive that the aerosol is the dominant reason of the visibility loss.

PS: the gases species can also impact the radiative transfer process of the earth system, but mainly in non-visible regions.

2. The calculation of visibility loss

Koschmiederp came up with an equation which connect the visibility and extinction coefficient $$b_{ext}$$ as follows:

$$V_R = 3.91/b_{ext}$$

• $$V_R$$ is the visibility reduction, unit in meters;

• $$b_{ext}$$ is the total extinction coffecient in all aspects (containing the four subset which I have already noted).

In the visible band, the scattering of gases can be omitted and the absorption of gases is mainly attributed to $$NO_2$$. As an empirical equation, the $$b_{ext}$$ can be derived as follows:

$$b_{ext} = 3f(RH)*[(NH_4)_2SO_4] + 3f(RH)*[(NH_4)_2SO_4] + 4f(RH)*[Organics] + 10[EC]+[Soil] +[0.6][Coarse\ mass]+ 3.3*[NO_2]+ 10$$

• $$f(RH)$$ is the function of relative humidity, it will increase with atmospheric RH.

• [Coarse mass] = [$$PM_{10}$$] - [$$PM_{2.5}$$]

• 10: the extinction of clean air

In this way, the visibility loss can be rebuilt. We can derive that the "there is a relationship between the concentrations of the chemical and the optical depth/visibility" as your second question.

3. Mass concentration and visibility

A figure I clipped from Chen et al., 2016 represent the relationship between $$PM_{2.5}$$ concentration and visibility. We can see the visibility is decrease when $$PM_{2.5}$$ increasing and the decreasing curve is sharp when the concentration is below 50 $${u}g/m^3$$. Besides, relative humility is a key factor here which high RH can worsen the deterioration of visibility. This is due to the hygroscopic behavior of some species (eg. $$(NH_4)_2SO_4$$)

• Nice. Much better than my answer :-) – daniel.heydebreck Jun 22 '17 at 14:23

Winter and Summer smog

There are two types of smog:

• winter smog:
• high emissions of soot and of $SO_2$ through heating with wood, coal, etc.
• $SO_2$ reacts to sulfuric acid => formation of particulate matter => reduced visibility
• summer smog (photochemical smog):
• strong sunlight and emissions of $NO_X$, $CO$ and VOCs
• emissions of primary particulate matter not necessary
• reaction of these air pollutants to other gaseous air pollutants (PAN, $O_3$, $HNO_3$) through photo-oxidation
• photo-oxidation of various VOCs => lump together to ultra-fine particles (secondary PM) => particles grow

Species that impact visibility

We 'need' the gaseous air pollutants to form secondary aerosol particles. The reduced visibility during winter and summer smog events is caused by these secondary aerosol particles (they scatter the light and, by this process, reduce visibility). The gaseous air pollutants might contribute to reduced visibility but their contribution is negligible compared to the aerosol impact.

Contribution of different aerosol species

The composition as well as the size distribution of the aerosol particles is important to determine the aerosol's optical properties. If you look into mass concentrations, a given mass of fine particles extincts more light than the same mass of coarse particles. If you look into composition (inorganic components), nitrate extincts more light than sea salt and sulfate. The extinction of organic aerosol depends on their composition (I have no idea which factors/species are relevant there).

If you are interested in further literature on the impact of the particle composition on the light extinction you might look into Pitchford et al. (2007). I didn't find a publication which quantifies the contribution of different particulate compositions/species to light extinction for smog. However, Pitchford et al. (2007) deals with light extinction for calculating the optical thickness from model data.

• I do not know how it has happened, but the (correct) DOI you used now links to spam. I recommend linking the journal's page as a next-best remedy. – GPhys Jun 21 '17 at 0:09
• Thank you for the comment. I updated the link accordingly. But strange redirect. I contacted the support of the journal published. – daniel.heydebreck Jun 21 '17 at 10:15

Smog is Air pollution + Water Vapour(Cloud)

• NO2 (Nitrogen Dioxide) : deep red-orange

• H2O (Water Vapour) : White

Nitrogen oxide, Sulfur oxide, Sulfur dioxide are said to be transparent gases.