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Where is obsidian found? Is it typically found on the surface or underground? If underground, how far under (meters or feet would be perfect)?

Also, is it found everywhere on Earth, or just in areas where volcanic activity is (or was recently) high?

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    $\begingroup$ Mostly underground, but can happen on the surface, too. $\endgroup$
    – o0'.
    Sep 22, 2014 at 15:35
  • $\begingroup$ I once found what I thought was obsidian, and it turned out to be slag from an ancient forge nearby. :) $\endgroup$
    – J. Musser
    Sep 23, 2014 at 1:09
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    $\begingroup$ Obsidian can be obtained by pouring water on lava. Oh, wait, this isn't gaming.se, nvm. $\endgroup$ Jun 30, 2015 at 6:13
  • $\begingroup$ As a side note, natural glass can be formed not only in volcanic settings, but also meteorite impacts and lightning strikes. Good examples are moldavite and fulgurites. Also, volcanic glass can occur in different shapes, in different environments, e.g. Pele's hair and pumice. $\endgroup$
    – user2821
    Jul 12, 2015 at 7:54

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The processes forming obsidian are not well understood because an active obsidian-forming eruption has never been recorded by humans. However, we can make many inferences from the composition of the rock and settings in which it is found.

Obsidian is more than 70% weight percent SiO2 (i.e. rhyolitic), but has less than 0.5 weight percent H2O, and almost 0% gas bubbles (vescicles). This is very unusual because high-silica magma typically also contains a high volatile content. That means they can contain up to 8% H2O, CO2 and other species that easily become gasses. Because the rock is "missing" water and has no gas bubbles, we know that the gas escaped the rock while it was molten. This process normally takes quite a bit of time, so you might think obsidian cools slowly so that all the volatiles could diffuse out of the rock without forming bubbles.

If you thought that, you would be wrong.

Here's why: The SiO2 is almost 100% in glass form (amorphous) rather than in crystals. Any crystals that do exist are microscopic. This is strong evidence saying the rock cooled quickly, because if it cooled slowly the SiO2 would have had time to organize itself into crystals as it cooled. Further supporting the idea that it cools quickly is the fact that it is not observed underground (as an intrusive rock, which would have cooled slowly.)

One way to explain this "low volatile, glassy texture" paradox is to say the lava was kept hot for long enough time that the gasses were able to escape, and then cooled very suddenly. Another possibility is that the parental magma was extremely dry (low-volatile) to begin with for some reason.

Modern humans have never seen obsidian erupt primarily because rhyolitic eruptions are rare. However, obsidian is rare even among rhyolitic eruptions, presumably because lots of open-system degassing followed by rapid cooling is an unusual phenomenon. There are many places in the world that seem to habitually produce obsidian and have produced enormous volumes of it. The Valles Caldera in New Mexico is a particularly good example, with a huge lava flow and several lava domes all constructed from obsidian. Similar lava domes called the Inyo Domes near Mono Lake, CA have been fundamental to the understanding of the behavior of stable isotopes in magmatic systems and are probably the most well-known outcrops of obsidian among geologists.

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    $\begingroup$ The origin or rhyolite/obsidian flows in not a "paradox" (or particularly problematic) to experienced field geologists. Whether or not anyone has witnessed the eruption of an obsidian (and I can think of reasons not to try) is not so important. Yes, the volatile and SiO2 content of a melt has a significant effect on the viscosity and rate of crystallization - that's been studied in laboratory experiments. There is much more to be learned about these lavas, but I would not characterize their origin as 'poorly understood.' $\endgroup$ Sep 23, 2014 at 16:04
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    $\begingroup$ @MarkRovetta is probably right that obsidian formation is not an unsolved mystery. I remember the "obsidian paradox" being presented in my undergrad lectures and don't remember who was teaching at the time. During my masters volcanologists talked about obsidan formation as if it wasn't particularly special. Worth nothing however that I didn't just mean humans have not see one happening -- I mean that no obsidian has been formed anywhere on the planet the last 200 years. The most recent obsidan I know of is Newberry Caldera at 1300 years old. $\endgroup$ Sep 23, 2014 at 19:23
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Obsidian is formed when a rhyolitic (or felsic) lava flows cool rapidly. This must mean that it's mostly available on the surface (and I think if you go near volcanos you can find pieces of Obsidian on the ground) because molten rock cools much faster above ground than it does below, allowing the melt to cool with small crystals (as opposed to intrusive rocks which have larger crystals). This means that Obsidian is an extrusive igneous rock.

I am betting that Obsidian is very common around most active volcanos around the world!

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    $\begingroup$ Thank you! I am by no means whatsoever, knowledgeable in Geology. (There aren't too many classes in High school either), however this was nice and simplistic enough to understand. :D $\endgroup$ Sep 21, 2014 at 21:56
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    $\begingroup$ This answer explains rhyolite, but says very little about obsidian. $\endgroup$ Sep 21, 2014 at 23:20
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I have seen it on the surface in some the lava fields of Iceland. This is consistent with @Neo answer.

Obsidian is not that often present, but if present, there is usually plenty around. It occurs in rather large pieces. This photo is from Landmannalaugar.

enter image description here

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  • $\begingroup$ There are also big hunks of the stuff at Obsidian Cliff in Yellowstone National Park. $\endgroup$ Sep 22, 2014 at 13:19

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