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Natural gas is mostly made of methane ($\ce{CH4}$). Methane can be produced as a result of microbes eating organic matter. But can it also be naturally formed without any assistance from organic matter? Perhaps in conditions such as those found on the early Earth?

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    $\begingroup$ Gasoline is not 'mostly made of methane'. You might have some more informed questions after doing some reading. $\endgroup$
    – Matt Hall
    Feb 2, 2016 at 0:28
  • $\begingroup$ Maybe you're thinking of natural gas. Gasoline, containing things like isooctane, butane, and 3-ethyltoluene, is a much more complex hydrocarbon than methane, which is the most simple of them. $\endgroup$
    – BillDOe
    Feb 2, 2016 at 1:34
  • $\begingroup$ <study.com/academy/lesson/…> $\endgroup$ Feb 4, 2016 at 10:19
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    $\begingroup$ It is the most common combination of the first and fourth most common elements in universe. And one of the most common compounds in the universe. I know of dozens of ways of making methane abiotically. You really might want to refine your question. $\endgroup$
    – John
    Dec 19, 2016 at 3:00
  • $\begingroup$ So your fundamental answer is yes, and then add a little background to it. Perhaps discuss some that may potentially be considerable sources currently or in likely previous Earth environments, maybe 1 or 2 interesting or funny, and I'd think you'd have a great answer to satisfy this question $\endgroup$ Dec 19, 2016 at 4:45

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The 'natural causes' of global methane emissions are, as you indicate, mostly of biological origin. To some extent it depends upon what you regard as 'natural'. There are many and differing estimates of global methane generation, of which I list a summary below. Those in bold you may regard as abiological. Values are in Mega-tonnes per year released to the atmosphere:

Wetlands 217

Fossil Fuels 96

Ruminants 89

Landfill 75

Geological sources 54

Freshwater 40

Biofuels 38

Rice growing 36

Oceans - DMS 20

Termites 11

Wildfires 10

It's a moot point as to whether degradation of dimethyl sulphide (DMS) is biological or not.

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    $\begingroup$ Do you have the source? $\endgroup$
    – f.thorpe
    Jan 3, 2017 at 2:41
  • $\begingroup$ I can't remember the issue but I jotted the above numbers down from an article in New Scientist, a year or two ago. $\endgroup$ Jan 4, 2017 at 7:31
  • $\begingroup$ You emphasized "oceans" but not "freshwater"? $\endgroup$
    – Spencer
    Jan 9, 2017 at 19:38
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Yes

It is one of most common compounds in the universe.

https://en.wikipedia.org/wiki/Methane#Extraterrestrial_methane

Which period of the early earth do you want to know about? the earliest atmosphere likely had less methane than now. http://science.sciencemag.org/content/308/5724/1014 But once life evolved methane rose. http://www.minersoc.org/pages/Archive-MM/Volume_62A/62a-2-751.pdf

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