Questions tagged [geochemistry]

The science that uses the tools and principles of chemistry to explain the mechanisms behind major geological systems.

29 questions with no upvoted or accepted answers
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How are Mauna Loa $\ce{CO2}$ monthly trends computed?

The problem I am trying to figure out how $\ce{CO2}$ concentration trends are computed in the data provided by the Earth Systems Research Laboratory Mauna Loa Observatory. The data contains monthly ...
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77 views

Predicting volcanic eruptions by experimentally proven volatile outgassing observations

In the abstract for the article Forecasting Etna eruptions by real-time observation of volcanic gas composition (Aiuppa et al. 2007), the authors assert that real time monitoring of volcanic volatiles,...
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Chloride and evaporation

I have a layered aquifer with water that contains high concentrations of calcium and sulfate (~400 mg/L Ca2+, ~1300 mg/L SO42-), at 50 cm below ground surface (bgs), 250 cm bgs and 300 cm bgs. The ...
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1answer
64 views

Relationship Between Ratio of Atmospheric Gases and Ocean Gases

A version of this question was posted in Chemistry SE and Worldbuilding SE but I've been told it wasn't appropriate to either SE. I was told to give this SE a chance. If you think it doesn't belong on ...
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Employment of Volcanologists and Petrologists

What industries or government departments hire volcanologists and igneous petrologists/geochemists in the United States?
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86 views

What causes a change in composition from basanite to nephelinite?

Can the change in composition from basanite to nephelinite (i.e. increasing alkalis with decreasing SiO2) be explained in terms of fractional crystallisation, or only by a decreasing degree of partial ...
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99 views

What reactions change seawater composition in hydrothermal systems?

Reactions in ocean floor hydrothermal systems are a significant contributor to the mass balance of several major elements in the oceans, in particular magnesium, calcium, sodium, potassium and sulfate....
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29 views

Can humidity changes induce stacking-sequence changes?

My understanding is that some minerals with layered crystal structures will reversibly absorb water with changes in humidity. Are there any minerals where this reversible absorption leads to a ...
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161 views

Where does molecular hydrogen in the atmosphere come from?

This figure from Wikipedia's Atmosphere of Earth shows a hydrogen fraction of 0.000055 percent by volume. Question: Where does molecular hydrogen in the atmosphere come from? Does this come directly ...
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53 views

Sulfate reduction

I read a document in which the authors stated "Sulfate and sulfide ( bisulfide and dihydrogen sulfide) both exist within a system just in varying proportions, and aqueous speciation is dependent on Eh/...
3
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65 views

Reason for higher content of Iodine and Copper than Iron in Seawater?

Does mineral weight contribute to the prevalence of minerals in seawater? Why is there five times more copper in seawater than Iron? Why is there 4000 times more strontium in seawather than Iron, ...
3
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129 views

Dolomite and calcite precipitation

In an engineered wetland, there is groundwater flow from an aquifer with a chemical composition that is rich in magnesium, calcium and sulfate. We are finding that the aquifer is consistently ...
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93 views

Does perchlorate(rocket fuel) and jet fuel make the salt and ground water near Cape Canaveral dangerous?

I've gotten into paddle surfing and I'm looking for a place to live and surf. I've been looking at an buying a condo in Cocoa Beach because of it’s proximity to Orlando and Cocoa’s decent but ...
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37 views

why igneous phosphate rocks contain less uranium than sedimentary rocks?

Sedimentary rock phosphates contain much higher concentrations of potentially hazardous elements (As, Cd, Cr,Pb, Se and U)than igneous rock phosphates. Why? Is it because U concentration in magmatic ...
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20 views

Formation of Hematite on Mars via Perchlorates as an Oxidizer

Hematite on Mars is generally thought to have formed either in pools of water or from volcanic activity. A comment to the answer to the question: How do hematite and magnetite form? states that ...
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34 views

Formation of dolomite

What are the kinetic barriers to dolomite precipitation? Does it precipitate out in solution as quickly as Calcite does?
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Can zircons be analysed by the (U+Th)/He after being ablated for analysis of U-Pb?

I have zircons that have been mounted in a resin block. They have been polished to approximately half way through the zircons (as is convention) and they have been ablated to attain the U-Pb or Pb-Pb ...
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71 views

Inverse model problem

I have a dataset for river water, rain water and geology (main elements and trace elements). I want to apportion the contribution of geology to water chemistry using for that purpose a model. I was ...
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24 views

Why was the temperature change greater in higher latitudes than in lower latitudes during the Paleocene/Eocene thermal maximum?

In the "Plankton cooled a greenhouse", which is the article written by Birger Schmitz, it is stated that the subtropical regions became warmer during the PETM(Paleocene/Eocene Thermal Maximum) but the ...
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solubility of rare earth sulphides at different pH?

Will rare earth sulfides in soil be more soluble in aqueous solutions with lower pH? How can I know whether these sulfides will dissolve better at low or high pH or will it not be affected?
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Why is sulfate reduction less important in freshwater sediments?

Is this due to increased salinity reducing sulfate concentration or the production of marsh gas converting sulfate to hydrogen sulfide or something else?
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73 views

How much hydrogen can be extracted from the deep continental crust?

Far below the earth's surface, hydrogen gas is continuously produced through serpentinization. At least some fraction of this hydrogen remains trapped in the deep continental crust; indeed, Soviet ...
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17 views

How do you interpret Oxygen Isotope changes?

In a paper I am reading, the authors note "large (5-7%) negative shifts in the oxygen isotopic composition of geologic proxy materials" (Davis 2008, pg. 102) in several regional basins. This is then ...
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1answer
51 views

Is weathering of rock a primary means of $\text{CO}_2$ scrubbing on primordial Earth?

I read somewhere that the reason Venus has a runaway greenhouse effect and Earth doesn't is because Venus failed to develop tectonic plates and instead formed a full tectonic plate enveloping the ...
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19 views

Do living things have a magnetic field capable of any level of solar protection?

I understand how anything with an electrical current have a magnetic field including living things. Would a densely populated rain forest or jungle have enough combined magnetic field among the living ...
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46 views

Pyrite oxidation

How much pyrite has to be oxidized to produce a sulfate concentration of 15 mM? If the solution initially has a pH of 8, roughly what would the pH drop to if there is no buffering of acidity?
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134 views

Mass balance for calculating mantle composition

I've seen some problem sets given without answers / solutions regarding how to calculate the composition of the mantle given solar composition (and assuming the same would apply to the Earth). For ...
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46 views

Weathering of silicates

I am trying to find a relationship between the silicate-rich rocks weathering products. For example I've found information regarding gabbro weathering in which, according the consulted source, in 100 ...
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100 views

Dry deposition of the total sulfate deposition in forested region

Sulfate is one important inorganic aerosol in the atmosphere. It's subject to removal by two main mechanisms. Wet deposition which include rain/wash-out and cloud deposition. Dry deposition ...